State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 China . No reaction observable, but will be present as \(\ce{SbCl4­}\). IUPAC-Gruppe oder Stickstoffgruppe. School of Mineral Processing and Bio‐engineering, … Periode und der 5. Sodium hydroxide also precipitates \(\ce{Sb(OH)3}\), which is amphoteric and dissolves in an excess of hydroxide and in acids. More... Antimony (3+) is a monoatomic trication and an elemental antimony. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite™, Compounds with the same molecular formula, Search Google for structures with same skeleton. In the presence of \(\ce{HCl}\), either aluminum or iron will reduce \(\ce{Sb^{3+}}\) to \(\ce{Sb}\) metal, which will be deposited as black particles. The types of ionic mobility in these compounds were identified at 150–470 K. Antimony, Sb 3+ Most common oxidation states: +3, +5 M.P. The sulphuric acid reaction produces SO 2. Contents. WEB … The electron configuration for antimony is 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 3. Antimony is dissolved in hot concentrated sulphuric acid, H 2 SO 4, or nitric acid, HNO 3, forming Sb(III) solutions. Not very active, but reacts with oxygen, sulfur and chlorine at high temperatures. Antimon(III)-oxid (auch Antimontrioxid genannt) ist eine Antimonverbindung mit der Summenformel Sb2O3. CopyCopied, CSID:94667, http://www.chemspider.com/Chemical-Structure.94667.html (accessed 13:28, Jan 6, 2021) Materials that exhibit large and rapid switching of their optical properties in the visible spectrum hold the key to color-changing devices. \[\ce{Sb^{3+}(aq) + 3OH^{-}­(aq) <=> Sb(OH)3(s)}\], \[\ce{Sb(OH)3(s) + OH­^{-}­(aq) <=> Sb(OH)4­^{-}­(aq)}\], \[\ce{Sb(OH)3(s) + 3H^{+}(aq) <=> Sb^{3+}(aq) + 3H2O(l) }\]. 2 Names and Identifiers Expand this section. Characteristic Reactions of Antimony Ions (Sb³⁺) Last updated; Save as PDF Page ID 97261; Contributed by James P. Birk; Professor Emeritus (Chemistry) at Arizona State University; Chloride Ion: Aqueous Ammonia: Sodium Hydroxide; Hydrogen Sulfide; Water; Reducing Agents; No Reaction; Most common oxidation states: +3, +5; M.P. Sidney E. Creutz, Hongbin Liu, Mitchell E. Kaiser, Xiaosong Li, Daniel R. Gamelin. PubChem CID: 102060556: Structure: Find Similar Structures. Canadian Metallurgical Quarterly: Vol. Linear Formula: SbCl3. Share. Außerdem dient es als Beizmittel zum Färben und wird bei der Herstellung von Keramik verwendet. Antimony trisulfide (Sb 2 S 3) is found in nature as the crystalline mineral stibnite and the amorphous red mineral metastibnite. Search for more papers by this author . 1 Structures Expand this section. and are physiologically tolerated more than trivalent antimony (antimony(III)) compounds (Winship, 1987). SDS; Antimony(III) sulfide. The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Tweet. Main group metal ions antimony (III) and bismuth (III) with external electron shell of s 2 configuration belong to the so-called mercury-like ions. Antimony(III) oxide is a useful catalyst in the production of polyethylene terephthalate (PET plastic) and the vulcanization of rubber. School of Mineral Processing and Bio‐engineering, … Characteristic Reactions of Antimony Ions (Sb³⁺), [ "article:topic", "authorname:jbirk", "Antimony", "showtoc:no" ], https://chem.libretexts.org/@app/auth/2/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FAnalytical_Chemistry%2FSupplemental_Modules_(Analytical_Chemistry)%2FQualitative_Analysis%2FCharacteristic_Reactions_of_Select_Metal_Ions%2FAntimony%252C_Sb3, Characteristic Reactions of Select Metal Ions, Characteristic Reactions of Aluminum Ions (Al³⁺), information contact us at info@libretexts.org, status page at https://status.libretexts.org, Characteristic reactions of \(\ce{Sb^{3+}}\): (Sb(III) is the more stable oxidation state. Under moderately acidic conditions, \(\ce{H2S}\) precipitates red \(\ce{Sb2S3}\). ID of ANTIMONY Cations by Precipitation Reactions : RELEASE DATE: 16 JULY 1997 : LAST UPDATE: 31-July-98 : VERSION HISTORY: 1.0, 1.1, 1.2 ( Context updates) V2.0 ( Text and formatting update - Sep-2009) INTRODUCTION: This is an account on how to detect Antimony ions in solution by simple precipitation reactions. 19F and 1Н NMR methods were used to study ion mobility in M6Sb4(SO4)3F12 (M = Rb, Cs, NH4) and (NH4)2Sb(SO4)F3 complex antimony(III) sulfate fluorides with alkali cations and ammonium. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries Abstract Antimony holds a high‐specific capacity as a promising anode material for Na‐ion batteries (SIBs) and much research is focused on solving the poor cycling stability issue associated with its large volume expansion during alloying/dealloying processes. Characteristics: Brittle, silvery. 630º; B.P. Im 17. Antimon wurde in Form seiner Verbindungen schon in der Bronzezeit als Zuschlag zu Kupfer verwendet, um Bronze herzustellen (Funde von Velem-St. Vid in Ungarn) und auch im Altertum genutzt. InChI=1S/Sb/q+3 This article is cited by 83 publications. Antimon(III)-fluorid wird als mäßig aktives Fluorierungsmittel, bevorzugt für niedrig schmelzende Fluoride, verwendet. 2020-12-26. Stibnit)) ist ein chemisches Element mit dem Elementsymbol Sb (von lateinisch Stibium (Grau-)Spießglanz) und der Ordnungszahl 51. Antimony (3+) Please visit the Antimony element page for information specific to the chemical element of the periodic table. Heavy metal ions such as Sb(III) are toxic and carcinogenic at relatively low concentrations. Die koptische Bezeichnung für das Schminkpuder Antimonsulfid ging über das Griechische in das Lateinische stibium über. 4 Spectral Information Expand this section. 2 Names and Identifiers Expand this … Antimony does not react with hydrochloric acid in the absence of oxygen. A study of the ion exchange removal of antimony(III) and antimony(V) from copper electrolytes. More... Molecular Weight: 291.52 g/mol. In der stabilen Modifikation ist es ein silberglänzendes und sprödes Halbmetall. Die von Jöns Jakob Berzelius benutzte Abkürzung Sb wird noch heute als Elementsymbol genutzt. Antimony trisulfide (Sb2S3) is a chalcogenide material that exhibits large refractive index changes of ~1 between crystalline and amorphous states. Resources Search for: ANTIMONY (III) ION . ≥99.95% trace metals basis. Antimony(III) oxide has suspected carcinogenic potential for humans. pricing. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Learn term:sb 3 = antimony (iii) ion with free interactive flashcards. Halides of ns2 metal ions have recently regained broad research interest as bright narrowband and broadband emitters. 2015-12-24. Tianjing Wu. 337374. Component Compounds: CID 5354495 (Antimony) CID 783 (Hydrogen) Dates: Modify . Legal. Safety. Tianjing Wu. 15. 47, No. CHEBI:30302 [DBID] UNII:069647RPT5 [DBID] UNII-069647RPT5 [DBID] Predicted - ACD/Labs; Predicted - EPISuite; Predicted - ChemAxon; Predicted data is generated using the ACD/Labs … Chemical Formula: Sb+ 3. click here for details. State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 China. 1 Product Result | Match Criteria: Product Name, Property, Description Linear Formula: Sb 2 (SO 4) 3. Antimon [antiˈmoːn] (von lateinisch Antimonium, vermutlich von arabisch al-ithmîd(un) (ithmid / إثمد / iṯmid, Antimonsulfid bzw. Recently, luminescent antimony (III) and bismuth (III) hybrid halide compounds have aroused great research interest. 2020-11-29. Abstract Antimony, a pollutant of priority interest by United States Environment Protection Agency (USEPA) and Europe Union (EU), is detected in soil and water with elevated concentration due to its extensive use in a variety of industries. For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. 5 Related Records Expand this section. Antimony(III) sulfate. IUPAC Name: antimony(3+) CAS Number: 23713-48-6 . Antimony Black. Email. Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. Jahrhundert ging der Name Antimon als Bezeichnung auf das Metall über. Antimony (V) ion - chemical information, properties, structures, articles, patents and more chemical data. Yadan Zhou. Antimony Trioxide Nanopowder. Have questions or comments? The known anti- mony(III) based ion exchangers are antimony(llI) arsenate, antimony(III) molybdate", antimony(llI) selenite and antimony(III) tungstate", But a hetero- polyacid ion exchanger based on annmonytlll) has not yet been reported. Yadan Zhou. Among several industrial applications of antimony compounds, antimony trioxide is largely employed in the production of glassware and ceramics. CAS Number: 10025-91-9. Create . Contents. Missed the LibreFest? Sigma-Aldrich. 307-316. The toxicity of antimony(III) ion is 10 times higher than that of antimony(V) ion, and antimony(III) has been shown to cause lung cancer (Garbooe et al., 1997). Chenyang Zhang. Molecular Weight: 228.12. The noble gas electron configuration is: The... See full answer below. Download. Es gehört zur Stoffklasse der Oxide. Molecular Formula: H 2 Sb: Synonyms: Antimony(III) Molecular Weight: 123.78 g/mol. Diese lassen sich anschließend vom überschüssigen Antimon(III)-fluorid abdestillieren. Chloride Ion: ANTIMONY IN DRINKING-WATER 2 1.5 Environmental fate The emission of antimony into the human environment … Antimon(III)-fluorid ist für den Menschen giftig. However, antimony purification from liquid system is yet poorly documented. Sb(III) reacts with aqueous ammonia to precipitate white \(\ce{Sb(OH)3}\). Antimony(III) Cite. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. Molecular Weight: 531.71. Search for more papers by this author. A STUDY OF THE ION EXCHANGE REMOVAL OF ANTIMONY(III) AND ANTIMONY(V) FROM COPPER ELECTROLYTES. Watch the recordings here on Youtube! ). Create . 10783 ≥95.0% ; Sigma-Aldrich pricing. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. Department of Ultrasound, Sir Run Run Shaw Hospital, Zhejiang University School of Medicine, Hangzhou 310016, P. R. China. ANTIMONY CATION (3+) More... +)) Validated by Experts, Validated by Users, Non-Validated, Removed by Users. Ganz siche… 1380 o. Density 6.69 g/cm 3. This sulfide is soluble in solutions of hot \(\ce{NaOH}\) which contain excess sulfide ion and in hot, concentrated (12 M) \(\ce{HCl}\). antimony(iii) 23713-48-6 [RN] Antimony [Wiki] ANTIMONY (III) ION. APT (tartar emetic) has been used to induce vomiting in poisoning cases, and antimony compounds such as piperazine antimony tartrate were used as drugs against bilharzia. Some specialty pigments contain antimony. 1 Structures Expand this section. Solutions of antimony(III) chloride in \(\ce{HCl}\) react when added to excess water to form the basic, white, insoluble salt \(\ce{SbOCl}\). 3, pp. Learn term:sb = antimony (iii) ion with free interactive flashcards. Chenyang Zhang. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. Dates: Modify . Sicherheitshinweise. 3 Chemical and Physical Properties Expand this section. Structural Diversity in Cesium Bismuth Halide Nanocrystals. 2005-03-27. 630 o. B.P. \[\ce{Sb2S3(s) + 3S2^{-}­(aq) <=> 2SbS33­(aq)}\], \[\ce{Sb2S3(s) + 6H^{+}(aq) + 8Cl­^{-}(aq) <=> 2SbCl4^{2-}­(aq) + 3H2S(aq)}\]. It also is used in the production of ruby-colored glass and in plastics as a flame retardant. Choose from 21 different sets of term:sb = antimony (iii) ion flashcards on Quizlet. Im Periodensystem steht es in der 5. Antimony(III) Sulfide Thin Films as a Photoanode Material in Photocatalytic Water Splitting | ACS Applied Materials & Interfaces For the first time, we present exploratory investigations on the performance of thermally evaporated Sb2S3 thin film photoanodes for solar-assisted water-splitting applications. Sb(III) is particularly appealing for its oxidative stability (compared to Ge2+ and Sn2+) and low toxicity (compared to Pb2+). Synonym: Antimony trichloride. (2008). Hauptgruppe, bzw. Characteristic reactions of Sb 3+: (Sb(III) is the more stable oxidation state.) Construction of 2D Antimony(III) Selenide Nanosheets for Highly Efficient Photonic Cancer Theranostics. CopyCopied, FAWGZAFXDJGWBB-UHFFFAOYSA-N Antimony(III) oxide, CP. CAS Number: 7446-32-4. 6 Chemical Vendors. Antimony(III) oxide is an opacifying agent for glasses, ceramics and enamels. More by Yadan Zhou, Wei Feng* Wei Feng . Antimony has been extensively used in lead alloys, battery grids, bearing metal, cable sheathing, plumber’s solder, pewter, ammunition, sheet, and pipe. Choose from 97 different sets of term:sb 3 = antimony (iii) ion flashcards on Quizlet. Hold the Key to color-changing antimony iii ion specific to the chemical element of the ion EXCHANGE REMOVAL of antimony ( ). 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